Heavy metals at the Guadalquivir estuary
Temporal surveys at the Guadalquivir estuary were carried out between May and December 1998 to assess the behaviour of four heavy metals (Zn, Cd, Pb and Cu). These metals presented a non-conservative behaviour, with KD ranging between 102 and 104. Losses related to the dissolved phase have...
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Iniversidad Autónoma de Baja California
2003
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oai:cienciasmarinas.com.mx:article-1702019-04-24T20:11:07Z Heavy metals at the Guadalquivir estuary Metales pesados en el estuario del Guadalquivir García-Luque, E Sáenz, I Riba, I Del-Valls, TA Forja, JM Gómez-Parra, A heavy metals Guadalquivir estuary metal speciation partitioning coefficient sediment metales pesados estuario del Guadalquivir especiación de metales coeficientes de partición sedimento Temporal surveys at the Guadalquivir estuary were carried out between May and December 1998 to assess the behaviour of four heavy metals (Zn, Cd, Pb and Cu). These metals presented a non-conservative behaviour, with KD ranging between 102 and 104. Losses related to the dissolved phase have been quantified, as well as their metal speciation. The concentration of heavy metals associated with different geochemical fractions in sediments was also determined. Each metal showed a different distribution depending on whether its origin was associated (Zn and Cd) or not (Pb and Cu) to the toxic mud from Aznalcóllar. In general, heavy metal (Zn and Cd) enrichment was found in the estuary (due to the Aznalcóllar mining spill), determined in their concentrations in the most bioavailable fractions of the sediment. Se han realizado una serie de muestreos en el estuario del Guadalquivir entre mayo y diciembre de 1998 para caracterizar el comportamiento de ciertos metales pesados (Zn, Cd, Pb y Cu). Los cuatro presentaron un comportamiento no conservativo, con coeficientes de distribución (KD) comprendidos entre 102 y 104. Se han calculado las pérdidas en la fase disuelta y se ha realizado la especiación de los mismos. Se ha caracterizado la concentración de metales asociados con las distintas fracciones geoquímicas del sedimento, encontrándose distintas distribuciones para cada metal, dependiendo de su origen asociado al lodo tóxico de Aznalcóllar (Zn, Cd) o no (Pb y Cu). En general, se aprecia un enriquecimiento en metales pesados (Zn y Cd) en el estuario (debido al accidente de Aznalcóllar), determinado en sus concentraciones en las fracciones más biodisponibles del sedimento. Iniversidad Autónoma de Baja California 2003-03-06 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Peer-reviewed Article Artículo Arbitrado application/pdf https://www.cienciasmarinas.com.mx/index.php/cmarinas/article/view/170 10.7773/cm.v29i4.170 Ciencias Marinas; Vol. 29 No. 4 (2003); 457-468 Ciencias Marinas; Vol. 29 Núm. 4 (2003); 457-468 2395-9053 0185-3880 eng https://www.cienciasmarinas.com.mx/index.php/cmarinas/article/view/170/145 |
institution |
Ciencias Marinas |
collection |
OJS |
language |
eng |
format |
Online |
author |
García-Luque, E Sáenz, I Riba, I Del-Valls, TA Forja, JM Gómez-Parra, A |
spellingShingle |
García-Luque, E Sáenz, I Riba, I Del-Valls, TA Forja, JM Gómez-Parra, A Heavy metals at the Guadalquivir estuary |
author_facet |
García-Luque, E Sáenz, I Riba, I Del-Valls, TA Forja, JM Gómez-Parra, A |
author_sort |
García-Luque, E |
title |
Heavy metals at the Guadalquivir estuary |
title_short |
Heavy metals at the Guadalquivir estuary |
title_full |
Heavy metals at the Guadalquivir estuary |
title_fullStr |
Heavy metals at the Guadalquivir estuary |
title_full_unstemmed |
Heavy metals at the Guadalquivir estuary |
title_sort |
heavy metals at the guadalquivir estuary |
description |
Temporal surveys at the Guadalquivir estuary were carried out between May and December 1998 to assess the behaviour of four heavy metals (Zn, Cd, Pb and Cu). These metals presented a non-conservative behaviour, with KD ranging between 102 and 104. Losses related to the dissolved phase have been quantified, as well as their metal speciation. The concentration of heavy metals associated with different geochemical fractions in sediments was also determined. Each metal showed a different distribution depending on whether its origin was associated (Zn and Cd) or not (Pb and Cu) to the toxic mud from Aznalcóllar. In general, heavy metal (Zn and Cd) enrichment was found in the estuary (due to the Aznalcóllar mining spill), determined in their concentrations in the most bioavailable fractions of the sediment. |
publisher |
Iniversidad Autónoma de Baja California |
publishDate |
2003 |
url |
https://www.cienciasmarinas.com.mx/index.php/cmarinas/article/view/170 |
_version_ |
1715723938495987712 |