C6 − C10 hydrocarbons from residual polyethylene

In this research work, combustible liquid hydrocarbons (gasoline) are obtained with a yield of 90% by means of pyrolysis of high-density polyethylene (HDPE) at 390 ± 5 °C over α−PbO catalyst. The catalytic mass is varied in 10, 15, 20 and 40% w/w using 10 g of HDPE for each experiment. The α−PbO is...

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Главные авторы:	Manjarrez Amaya, Karla Michelle, Villalón López, Ulises Alejandro, Avalos Borja, Miguel, Quintana Melgoza, Juan Manuel
Формат:	Online
Язык:	spa
Опубликовано:	Universidad Autónoma de Baja California 2020
Online-ссылка:	https://recit.uabc.mx/index.php/revista/article/view/35
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id	recit-article-35
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spelling	recit-article-352022-10-20T22:42:01Z C6 − C10 hydrocarbons from residual polyethylene Hidrocarburos C6−C10 a partir de polietileno residual Manjarrez Amaya, Karla Michelle Villalón López, Ulises Alejandro Avalos Borja, Miguel Quintana Melgoza, Juan Manuel Residual HDPE pyrolysis α−PbO liquid hydrocarbons. PEAD residual pirólisis α−PbO hidrocarburos líquidos. In this research work, combustible liquid hydrocarbons (gasoline) are obtained with a yield of 90% by means of pyrolysis of high-density polyethylene (HDPE) at 390 ± 5 °C over α−PbO catalyst. The catalytic mass is varied in 10, 15, 20 and 40% w/w using 10 g of HDPE for each experiment. The α−PbO is synthesized at 550 °C in an air atmosphere for 1 hour. Liquid products are characterized by Fourier transform infrared spectroscopy (FT-IR) and gas chromatography and mass spectrometry (GC/MS). The experimental optimal ratio of HDPE/α−PbO for the conversion of residual polyethylene is 20% α−PbO. The analyzes by FT-IR and GC/MS, allow to confirm that the liquids obtained correspond to hydrocarbons with chains in a range of 6 to 10 carbons (C6–C10) and contain an average heat of combustion of 10.9492 kcal/g with potential application as alternative fuels. En este trabajo de investigación se obtienen hidrocarburos liquidos combustibles (gasolina) con rendimiento del 90% por medio de pirólisis del polietileno de alta densidad (PEAD) a 390 ± 5 °C sobre el catalizador α−PbO. La masa catalítica se varía en 10, 15, 20 y 40% p/p utilizando 10 g de PEAD por cada experimento. El α−PbO se sintetizó a 550 °C en atmósfera de aire durante 1 hora. Los productos líquidos son caracterizados por espectroscopia infrarroja con transformada de Fourier (FT-IR) y cromatografía de gases y espectrometría de masas (GC/MS). La relación óptima experimental de PEAD/α−PbO para la conversión del polietileno residual es 20% α−PbO. Los análisis por FT-IR y GC/MS, permiten corroborar que los líquidos obtenidos corresponden a hidrocarburos con cadenas en un intervalo de 6 a 10 carbonos (C6–C10) y contienen un calor de combustión promedio de 10.9492 kcal/g con potencial aplicación como combustibles alternativos. Universidad Autónoma de Baja California 2020-01-21 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Research article Artículo de investigación application/pdf text/html application/xml https://recit.uabc.mx/index.php/revista/article/view/35 10.37636/recit.v317175 REVISTA DE CIENCIAS TECNOLÓGICAS; Vol. 3 No. 1 (2020): January-March; 71-75 REVISTA DE CIENCIAS TECNOLÓGICAS; Vol. 3 Núm. 1 (2020): Enero-Marzo; 71-75 2594-1925 spa https://recit.uabc.mx/index.php/revista/article/view/35/39 https://recit.uabc.mx/index.php/revista/article/view/35/40 https://recit.uabc.mx/index.php/revista/article/view/35/161 Copyright (c) 2020 Karla Michelle Manjarrez Amaya, Ulises Alejandro Villalón López, Miguel Avalos Borja, Juan Manuel Quintana Melgoza http://creativecommons.org/licenses/by/4.0
institution	RECIT
collection	OJS
language	spa
format	Online
author	Manjarrez Amaya, Karla Michelle Villalón López, Ulises Alejandro Avalos Borja, Miguel Quintana Melgoza, Juan Manuel
spellingShingle	Manjarrez Amaya, Karla Michelle Villalón López, Ulises Alejandro Avalos Borja, Miguel Quintana Melgoza, Juan Manuel C6 − C10 hydrocarbons from residual polyethylene
author_facet	Manjarrez Amaya, Karla Michelle Villalón López, Ulises Alejandro Avalos Borja, Miguel Quintana Melgoza, Juan Manuel
author_sort	Manjarrez Amaya, Karla Michelle
title	C6 − C10 hydrocarbons from residual polyethylene
title_short	C6 − C10 hydrocarbons from residual polyethylene
title_full	C6 − C10 hydrocarbons from residual polyethylene
title_fullStr	C6 − C10 hydrocarbons from residual polyethylene
title_full_unstemmed	C6 − C10 hydrocarbons from residual polyethylene
title_sort	c6 − c10 hydrocarbons from residual polyethylene
description	In this research work, combustible liquid hydrocarbons (gasoline) are obtained with a yield of 90% by means of pyrolysis of high-density polyethylene (HDPE) at 390 ± 5 °C over α−PbO catalyst. The catalytic mass is varied in 10, 15, 20 and 40% w/w using 10 g of HDPE for each experiment. The α−PbO is synthesized at 550 °C in an air atmosphere for 1 hour. Liquid products are characterized by Fourier transform infrared spectroscopy (FT-IR) and gas chromatography and mass spectrometry (GC/MS). The experimental optimal ratio of HDPE/α−PbO for the conversion of residual polyethylene is 20% α−PbO. The analyzes by FT-IR and GC/MS, allow to confirm that the liquids obtained correspond to hydrocarbons with chains in a range of 6 to 10 carbons (C6–C10) and contain an average heat of combustion of 10.9492 kcal/g with potential application as alternative fuels.
publisher	Universidad Autónoma de Baja California
publishDate	2020
url	https://recit.uabc.mx/index.php/revista/article/view/35
_version_	1792095360757268480

C6 − C10 hydrocarbons from residual polyethylene

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